Introduction
If fly ash is collected separately from bottom ash and flue gas cleaning residues, two different methods may be applied to remove or immobilise heavy metals from fly ash:
Acid washing
Neutral washing
If fly ash is collected separately from bottom ash and flue gas cleaning residues, two different methods may be applied to remove or immobilise heavy metals from fly ash:
Acid washing
Neutral washing
Acidic fly ash washing uses acidic scrubber blowdown to wash out the heavy metals from fly ash. Heavy metals can be recovered in the effluent treatment stage and recycled. After that, the fly ash can be landfilled together with the bottom ash.
The aim of this process is to transform fly ash into a stable, leach-proof matrix. Neutral, easily soluble salts are extracted in a cascade of stirred vessels. By controlling pH in a slightly alkaline range, soluble heavy metals are precipitated. Washing liquid is separated from the solids by filtration and cleaned in the effluent treatment stage. Dewatered solids are mixed with hydraulic binders to form a solid, stable and leach-resistant matrix when landfilled.